Influence of Hairy Basil Seed Mucilage Concentrations on Cobalt Ferrite Nanoparticle Magnetic Parameters Synthesized by the Sol-Gel Method
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Abstract
In this work, the desire to synthesize cobalt ferrite nanoparticles. Using the sol-gel technique with basil seed mucilage as a chelating agent. Study of the correlation between the gel concentration and magnetic parameters such as saturated magnetization (Ms), remanence magnetization (Mr), coercivity (Hc), and squareness. The final product of the sol-gel reaction is used to measure thermal behavior with TGA. The calcine temperature was then set to prepare the samples at 600°C for 10 hours. The cobalt ferrite phase is fully visible in the XRD pattern when the gel concentration is 20% or higher. The sample shows up as a flake in the SEM image and transforms into a larger cluster as the gel concentration increases. The hysteresis loop curve was measured using the VSM technique, which is used to investigate magnetic properties. The best saturation magnetization was measured at 71.41 emu/g, and squareness is 0.47 with a 25% chelating concentration.
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References
Raghavender, A. T. & Jadhav, K. M. (2009). Dielectric properties of Al-substituted Co ferrite nanoparitcles. Bulletin of Materials Science, 32(6), 575 – 578.
Young, S. K. (2002). Overview of Sol-Gel Science and Technology. Available from http://www.arl.army.mil. Accessed date: 27 June 2004.
Goldman, A. (2006). Modern Ferrite Technology. 2nd ed. Pittsburgh: Spinger.
Mathew, D. S. & Juang, R. S. (2007). An overview of the structure and magnetism of spinel ferrite nanoparticles and their synthesis in micromulsions. Chemical Engineering Journal, 129, 51-65.
Dey, C., et al. (2017). Improvement of drug delivery by hyperthermia treatment using magnetic cubic cobalt ferrite nanoparticles. Journal of Magnetism and Magnetic Materials, 427, 168 – 174.
Sharifi, I., et al. (2012). Ferrite-based magnetic nanofluids used in hyperthermia applications. Journal of Magnetism and Magnetic Materials, 324, 903 – 915.
Zhang, K., et al. (2011). Magnetic behavior of nanocrystalline CoFe2O4. Journal of Magnetism and Magnetic Materials, 323, 1616 – 1622.
Puttajukr, S. (2003). Physical, Rheological and Engineering Properties of Rubber. Pattani: Office of Academic Resources, Prince of Songkla University, Pattani Campus. (in Thai)
Maensiri, S., et al. (2007). A simple route to synthesize nickel ferrite (NiFe2O4) nanoparticles using egg white. Scripta Materialia, 56, 797 – 800.
Laokul, P., et al. (2011). Characterization and magnetic properties of nanocrystalline CuFe2O4, NiFe2O4, ZnFe2O4 powders prepared by the Aloe vera extract solution. Current Applied Physics, 11, 101 – 108.
Hunyek, A. (2018). Use of biopolymers for chetating agent in the synthesis of magnetic cobalt ferrite nanoparticles. Pathumwan Academic Journal, 8(21), 45 - 56. (in Thai)
Hunyek, A., et al. (2017). Sago starch: chelating agent in Sol-gel synthesis of cobalt ferrite nanoparticles. Journal of the Australian Ceramic Society, 53, 173 – 176.
Hunyek, A.,et al. (2022). Tapioca starch in the sol-gel synthesis of cobalt ferrites with divalent cation substitutions. Karbala International Journal of Modern Science, 8, 397 – 405.
Sears, M.E. (2013). Chelation: Harnessing and enhancing heavy metal detoxification – a review. The Scientific World Journal, 2013, 219840.
Al-Qahtani, K. M. A. (2017). Extraction heavy metals from contaminated water using chelating agents. Oriental journal of Chemistry, 33, 1698 – 1704.
Jacob, R.H., et al. (2022). Chelated amino acids: biomass sources, preparation, properties and biological activities. Biomass Conversion and Biorefinery, unpaged.
Western, T. L. (2012). The sticky tale of seed coat mucilages: production, genetics, and role in seed germinaition and disperal. Seed Science Research, 22, 1 – 25.
Zhou, D. (2022). Production, composition, and ecological function of sweet-basil-seed mucilage during hydration. Horticulutrae, 8(4), 327.
Hunyek, A., et al. (2011). Formation of cobalt ferrites from aqueous solutions of metal nitrates containing PVA: effects of the amount of PVA and annealing temperature. Journal of the Ceramic Society of Japan, 119(6), 541 – 543.
Hunyek, A., et al. (2012). Structural and magnetic properties of cobalt ferrites synthesized using sol-gel techiques. Material Science-Poland, 30, 278 – 281.
Adeela, A., et al. (2015). Influence of manganese substitution on structural and magnetic properties of CoFe2O4 nanoparticles. Journal of Alloys and Compounds, 639, 533 – 540.
Qin, R.,et al. (2009). Synthesis of well-dispersed CoFe2O4 nanoparticles via PVA-assisted low-temperature solid state process. Journal of Alloys and Compounds, 482, 508–511.
Reddy, C. V., et al. (2015). Investigation of structural, thermal and magnetic properties of cadmiun substituted cobalt ferrite nanoparticles. Superlattices and Microstructures, 82, 165 – 173.
Aswani, T., et al. (2014). Spectral characterizations of undoped and Cu2+ doped CdO nanopowder. Journal of Molecular Structure, 1063, 178 – 183.
Gaffoor, A. & Ravinder, D. (2014). Characterization of magnesium substituted nickel nano ferrites synthesized by cirate-gel auto combustion method. International Journal of Engineering Research and Applications, 4, 60 – 66.
Rakshit, R., et al. (2015). Charge transfer mediated magnetic response of cobalt ferrite nanoparticles. Materials Letters, 151, 64 – 67.
Naseri, M. G., et al. (2010). Simple synthesis and characterization of cobalt ferrite nanoparticles by a thermal treatment method. Journal of Nanomaterials, 2010, 907686.
Chinnasamy, C. N., et al. (2003). Synthesis of size-controlled cobalt ferrite particles with high coercivity and squareness ratio. Journal of Colloid and Interface Science, 263(1), 80-83.
Baldi, G., et al. (2007). Cobalt ferrite nanoparitcles: The control of the particle size and surface state and their effects on magnetic properties. Journal of Magnetism and Magnetic Materials, 311, 10- 16.
Silva, J. B., et al. (2004). Influence of heat treatment on cobalt ferrite ceramic powders. Materials Science and Engineering B, 112(2-3), 182-187.
Parekh, K. (2010). Effect of preparative conditions on magnetic properties of CoFe2O4 nanoparticles. Indian Journal of Pure & Applied Physics, 48, 581-585.