Chemical Modification of Unwanted Flora (Hanguana Malayana) as Activated Carbon to Remove Methylene Blue and Congo Red
DOI:
https://doi.org/10.14456/nujst.2022.26Keywords:
methylene blue, Congo red, activated carbon, adsorption, Hanguana malayanaAbstract
Wastewater is well-known hot issue of environmental pollutions that require a solution hurriedly. Organic dye is a severe toxic contaminant in water. In this work, Hanguana Malayana used as carbon source was chemically activated as activated carbon. The biochar was carried out by the pyrolysis through the heat treatment at 200 °C under low O2 atmosphere. The resulting powder was activated by using ZnCl2 under hydrothermal conditions at 120 °C for 24 h, and further heat-treated at 300 °C for 1 h. The as-prepared product was verified by XRD, FT-IR, SEM, and BET. There were large surface area and many functional groups on the surface of the as-prepared product. All amounts of methylene blue (20 ppm, 50 mL) were removed by 50 mg of activated carbon, meanwhile very few amounts of Congo red (20 ppm, 50 mL) were eliminated. This work showed the benefits on increasing an add-value of Hanguana Malayana by the chemical process together with eliminating unwanted flora and toxic dye chemicals in water.
References
Fei, F., Gao, Z., Wu, H., Wurendaodi, W., Zhao, S., & Asuha, S. (2020). Facile solid-state synthesis of Fe3O4/kaolinite nanocomposites for enhanced dye adsorption. Journal of Solid State Chemistry, 291, 121655. https://doi.org/10.1016/j.jssc.2020.121655
Gautam, P. K., Gautam, R. K., Banerjee, S., Lofrano, G., Sanroman, M. A., Chattopadhyaya, M. C., & Pandey, J. D. (2015). Preparation of activated carbon from Alligator weed (Alternenthera philoxeroids) and its application for tartrazine removal: Isotherm, kinetics and spectroscopic analysis. Journal of Environmental Chemical Engineering, 3, 2560-2568. https://doi.org/10.1016/j.jece.2015.08.004
Intachai, S., Boaulan, A., & kongsune, P. (2020). Preparation of dodecylsulfate modified CoAl-layered double hydroxide and dye removal. Rajamangala University of Technology Srivijaya Research Journal, 12, 275–284. https://li01.tci-thaijo.org/index.php/rmutsvrj/article/view/245399
Intachai, S., Pimchan, P., & Sumanatrakul, P. (2019). Synthesis of NiAl–layered double oxide as inorganic adsorbent for eliminating dye from solution. Naresuan University Journal: Science and Technology, 27, 66-74. http://www.journal.nu.ac.th/NUJST/article/view/Vol-27-No-4-2019-66-74
Lellis, B., Fávaro-Polonio, C. Z., Pamphile, J. A., & Polonio, J. C. (2019). Effects of textile dyes on health and the environment and bioremediation potential of living organisms. Biotechnology Research and Innovation, 3, 275-290. https://doi.org/10.1016/j.biori.2019.09.001
Lopez-Ramon, M. V., Stoeckli, F., Moreno-Castilla, C., & Carrasco-Marin, F. (1999). On the characterization of acidic and basic surface sites on carbons by various techniques. Carbon, 37, 1215-221. https://doi.org/10.1016/S0008-6223(98)00317-0
Minisy, I. M., Salahuddin, N. A., & Ayad, M. M. (2021). Adsorption of methylene blue onto chitosan–montmorillonite/polyaniline nanocomposite. Applied Clay Science, 203, 105993. https://doi.org/10.1016/j.clay.2021.105993
Moosavi, S., Lai, C. W., Gan, S., Zamiri, G., Pivehzhani, O. A., & Johan, M. R. (2020). Application of efficient magnetic particles and activated carbon for dye removal from wastewater. ACS Omega, 5, 20684-20697. https://dx.doi.org/10.1021/acsomega.0c0190
Palza, H., Delgado, K., & Govan, J. (2019). Novel magnetic CoFe2O4/layered double hydroxide nanocomposites for recoverable anionic adsorbents for water treatment. Applied Clay Science, 183, 105350. https://doi.org/10.1016/j.clay.2019.105350
Rajasulochana, P., & Preethy, V. (2016). Comparison on efficiency of various techniques in treatment of waste and sewage water – A comprehensive review. Resource-Efficient Technologies, 2, 175-184. https://doi.org/10.1016/j.reffit.2016.09.004
Salem, S., Teimouri, Z., & Salem, A. (2020). Fabrication of magnetic activated carbon by carbothermal functionalization of agriculture waste via microwave-assisted technique for cationic dye adsorption. Advanced Powder Technology, 31, 4301-4309. https://doi.org/10.1016/j.apt.2020.09.007
Sanmuga Priya, E., & Senthamil Selvan, P. (2017). Water hyacinth (Eichhornia crassipes) - An efficient and economic adsorbent for textile effluent treatment - A review. Arabian Journal of Chemistry, 10, S3548-S3558. https://doi.org/10.1016/j.arabjc.2014.03.002
Tang, J., Mu, B., Zong, L., & Wang, A. (2018). One-step synthesis of magnetic attapulgite/carbon supported NiFe-LDHs by hydrothermal process of spent bleaching earth for pollutants removal. Journal of Cleaner Production, 172, 673-685. https://doi.org/10.1016/j.jclepro.2017.10.181
Tian, D., Xu, Z., Zhang, D., Chen, W., Cai, J., Deng, H., … Zhou, Y. (2019). Micro-mesoporous carbon from cotton waste activated by FeCl3/ZnCl2: Preparation, optimization, characterization and adsorption of methylene blue and eriochrome black T. Journal of Solid State Chemistry, 269, 580-587. https://doi.org/10.1016/j.jssc.2018.10.035
Tkaczyk, A., Mitrowska, K., & Posyniak, A. (2020). Synthetic organic dyes as contaminants of the aquatic environment and their implications for ecosystems: A review. Science of the Total Environment, 717, 137222. https://doi.org/10.1016/j.scitotenv.2020.137222
Xu, H., Gao, B., Cao, H., Chen, X., Yu, L., Wu, K., … Fu, J. (2014). Nanoporous activated carbon derived from rice husk for high performance supercapacitor. Journal of Nanomaterials, 2014, 714010. https://doi.org/10.1155/2014/714010
Yagub, M. T., Sen, T. K., Afroze, S., & Ang, H. M. (2014). Dye and its removal from aqueous solution by adsorption: A review. Advances in Colloid and Interface Science, 209, 172-184. https://doi.org/10.1016/j.cis.2014.04.002
Downloads
Published
Issue
Section
License
Copyright (c) 2022 Naresuan University Journal: Science and Technology
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.